Research helps solar technology become more affordable

Scientists at the University have found a way to accelerate the uptake of solar technology by increasing the environmental safety of perovskite solar cells.

Perovskite solar cells have attracted interest because, unlike silicon solar cells, they can be mass produced through roll-to-roll processing. Additionally, they are light and colourful, with the versatility to be used in non-traditional settings such as windows and contoured roofs. However, up until now, application has been impacted by potential environmental risks. Perovskite solar cells contain lead, a cumulative toxin, and if the cells get damaged, lead ions may leak.

Taking lessons from nature, Professor Brian Saunders and Dr David Lewis have devised a way to eliminate the lead release from broken cells. Using a bioinspired mineral called hydroxyapatite, a major constituent of human bone, they have created a ‘failsafe’ which captures the lead ions in an inorganic matrix. As a result, if cells are damaged, toxins are stored in an inert mineral, rather than released in the environment.

In a dual success, The Engineering and Physical Sciences Research Council (EPSRC)-funded project found that through the addition of hydroxyapatite, the efficiency of perovskite solar cell increased to around 21%. This compares to around 18% efficiency for control cells with no added hydroxyapatite.

The research team hope that the cells will bring forward the large-scale application of perovskite solar cell technology. Professor Brian Saunders, Professor of Polymer and Colloid Chemistry at the School of Materials, said: “Through increasing the inherent safety of perovskite solar cells, we hope our research will provide a helping hand to the wider deployment of solar technology as we strive to achieve net zero CO2 emissions.”

The research was reported in: ‘Bioinspired scaffolds that sequester lead ions in physically damaged high efficiency perovskite solar cells’ in Chemical Communications.